Organic letters

Copper (0)-Induced Deselenative Insertion of N, N-Disubstituted Selenoamides into Acetylenic C− H Bond Leading to Propargylamines

T Mitamura, A Ogawa

文献索引：Mitamura, Takenori; Ogawa, Akiya Organic Letters, 2009 , vol. 11, # 10 p. 2045 - 2048

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被引用次数: 17

摘要

Carbenoid species, such as Fischer-type carbene complexes, Schrock-type carbene complexes, and other metal carbene complexes, have unique reactivity and properties; therefore, they have been often utilized as key intermediates in organic synthesis.(1, 2) Although alkoxycarbenes are widely studied and employed in many methods, there are many fewer examples for aminocarbenes compared with alkoxycarbenes.(3) Selenoamides, which have a ...