N-[hydroxy (dimethyl) silylmethyl]-N, N′-propylene urea hydrochloride: Synthesis and structure

…, SA Pogozhikh, YE Ovchinnikov, NF Lazareva

文献索引：Pestunovich, Vadim A.; Albanov, Alexander I.; Lazareva, Nataliya F.; Pogozhikh, Sergey A.; Ovchinnikov, Yuri E. Journal of Molecular Structure, 2012 , vol. 1024, p. 136 - 141,6

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被引用次数: 5

摘要

The new N-chlorodimethylsilylmethyl-N′-trimethylsilyl-N, N′-propylene urea 5 was synthesized by trans-silylation reaction of N, N′-bis (trimethylsilyl)-N, N′-propylene urea 4 with ClCH2SiMe2Cl. Mild hydrolysis of compound 5 results in the formation of N-[hydroxy (dimethyl) silylmethyl]-N, N′-propylene urea hydrochloride 6. The structure of the studied compounds in solution was determined by 1H, 13C and 29Si NMR spectroscopy and by X ...