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Optimization of the reaction conditions in the lipase-catalyzed synthesis of structured triglycerides

U Schmid, UT Bornscheuer, MM Soumanou…

文献索引:Schmid; Bornscheuer; Soumanou; McNeill JAOCS, Journal of the American Oil Chemists' Society, 1998 , vol. 75, # 11 p. 1527 - 1531

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被引用次数: 87

摘要

Abstract Structured triglycerides of the ABA-type, containing one type of fatty acid (A) in the sn-1 and sn-3 positions and a second type of fatty acid (B) in the sn-2 position of the glycerol, were synthesized using lipases. The highest yields and purities were achieved in a two-step process, where a triglyceride of the B-type was subjected to an alcoholysis reaction in an organic solvent catalyzed by sn-1, 3-regiospecific lipases yielding the corresponding ...