Tetrahedron Letters

Total stereospecificity in free radical intramolecular addition: Cyclisation of cis and trans 1-methyl 4-hexenyl N-chloroamines by means of metallic salts

JL Bougeois, L Stella, JM Surzur

文献索引：Bougeois, Jean-Luc; Stella, Lucien; Surzur, Jean-Marie Tetrahedron Letters, 1981 , vol. 22, p. 61 - 64

被引用次数: 25

摘要

Abstract Extremely high stereospecificity (up to 100% diastereoisomeric purity) can be obtained for the metallic salts radical cyclisation of the cis and trans 1-methyl 4-hexenyl N- choloroamines. A possible mechanism for the highly effective trans-addition using metal- complexed aminyl radical is proposed.

~90%

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