Tetrahedron Letters

Total stereospecificity in free radical intramolecular addition: Cyclisation of cis and trans 1-methyl 4-hexenyl N-chloroamines by means of metallic salts

JL Bougeois, L Stella, JM Surzur

Index: Bougeois, Jean-Luc; Stella, Lucien; Surzur, Jean-Marie Tetrahedron Letters, 1981 , vol. 22, p. 61 - 64

Full Text: HTML

Citation Number: 25

Abstract

Abstract Extremely high stereospecificity (up to 100% diastereoisomeric purity) can be obtained for the metallic salts radical cyclisation of the cis and trans 1-methyl 4-hexenyl N- choloroamines. A possible mechanism for the highly effective trans-addition using metal- complexed aminyl radical is proposed.

~90%

Reactions of organic halides with olefins under Ni o-catalys...

[Sustmann, Reiner; Hopp, Peter; Holl, Peter Tetrahedron Letters, 1989 , vol. 30, # 6 p. 689 - 692]

Formation and reactions of monovalent carbon intermediates. ...

[Strausz,O.P. et al. Journal of the American Chemical Society, 1974 , vol. 96, # 18 p. 5723 - 5732]

Catalytic epoxidation of alkenes with oxone

[Denmark, Scott E.; Forbes, David C.; Hays, David S.; DePue, Jeffrey S.; Wilde, Richard G. Journal of Organic Chemistry, 1995 , vol. 60, # 5 p. 1391 - 1407]

Facile syntheses for (5Z, 9Z)-5, 9-hexadecadienoic acid,(5Z,...

[Bestmann; Koschatzky; Schaetzke; et al. 1981 , vol. No. 9, p. 1705 - 1720]