Macromolecules

Synthesis and recognition properties of polymers containing embedded binding sites

K Das, H Nakade, J Penelle, VM Rotello

文献索引：Das, Kanad; Nakade, Hiroshi; Penelle, Jacques; Rotello, Vincent M. Macromolecules, 2004 , vol. 37, # 2 p. 310 - 314

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被引用次数: 23

摘要

We report the synthesis and guest affinities of polymers featuring a single recognition site in the middle of the polymer chain. These polymers were synthesized from difunctional initiators based on the 2, 6-diacyldiaminopyridine moiety. Binding efficiencies were experimentally determined using a complementary fluorescent guest, N (10)-isopropyl flavin. The effect of polymer length on recognition was explored by the synthesis of 5 PMMA ...