Dimerization and trapping of diazirinyl radicals

RA Thompson, JS Francisco…

文献索引：Thompson, Robert A.; Francisco, Joseph S.; Grutzner, John B. Physical Chemistry Chemical Physics, 2004 , vol. 6, # 4 p. 756 - 765

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被引用次数: 3

摘要

Computational and experimental methods have been utilized to examine the facile dimerization of diazirinyl radicals. Two potential dimers were investigated using density functional theory. Both were shown to have low-barrier reaction coordinates leading to formation of HCN and N2. A cross-over experiment was employed to establish the relative contributions of C–N and N–N dimers towards product formation. The N–N dimerization ...