Computational and experimental methods have been utilized to examine the facile dimerization of diazirinyl radicals. Two potential dimers were investigated using density functional theory. Both were shown to have low-barrier reaction coordinates leading to formation of HCN and N2. A cross-over experiment was employed to establish the relative contributions of C–N and N–N dimers towards product formation. The N–N dimerization ...
![2,4,6-triphenyl-1,3,5-triazabicyclo[3.1.0]hexane Structure](https://image.chemsrc.com/caspic/123/56782-50-4.png)
