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The Journal of Organic Chemistry

Slow nitrogen inversion due to intramolecular hydrogen bonding. Slow nitrogen inversion in diethyl 2-aziridinylphosphonate from the paramagnetic-induced shifts in …

S Rengaraju, KD Berlin

文献索引:Rengaraju,S.; Berlin,K.D. Journal of Organic Chemistry, 1972 , vol. 37, # 21 p. 3304 - 3310

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被引用次数: 24

摘要

Retardation of pyramidal inversion of nitrogen was observed in diethyl 2- aziridinylphosphonate due to intramolecular hydrogen bonding. The presence of two invertomers has been shown by the nuclear magnetic resonance (nrnr) studies using the paramagnetic shift reagent tris (dipivalomethanato) europium (III)[Eu (DPhI) 3] ani benzene solvent shift studies.