Slow nitrogen inversion due to intramolecular hydrogen bonding. Slow nitrogen inversion in diethyl 2-aziridinylphosphonate from the paramagnetic-induced shifts in …
S Rengaraju, KD Berlin
文献索引:Rengaraju,S.; Berlin,K.D. Journal of Organic Chemistry, 1972 , vol. 37, # 21 p. 3304 - 3310
Retardation of pyramidal inversion of nitrogen was observed in diethyl 2- aziridinylphosphonate due to intramolecular hydrogen bonding. The presence of two invertomers has been shown by the nuclear magnetic resonance (nrnr) studies using the paramagnetic shift reagent tris (dipivalomethanato) europium (III)[Eu (DPhI) 3] ani benzene solvent shift studies.