The Journal of Organic Chemistry

… synthesis of. beta.-aryl-or. beta.-alkenyl-. beta.-methyl-. alpha.,. beta.-unsaturated carbonyl compounds by palladium catalyzed reaction of 1, 2-dien-4-ols with aryl or …

I Shimizu, T Sugiura, J Tsuji

文献索引：Shimizu, Isao; Sugiura, Teruo; Tsuji, Jiro Journal of Organic Chemistry, 1985 , vol. 50, # 4 p. 537 - 539

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被引用次数: 49

摘要

Pd (eq 1) R A+ R'X R-R'nylpalladium complexes, formed in situ from phenyl or alkenyl halides and a Pd (0) complex, reacts with 1, Zdienes regioselectively to form (2-phenyl-or (2- alkenyl-a-allyl)-palladium intermediates which undergo amination to give 2-phenyl or 2- alkenyl allylic amines (eq 2). 2 In the reaction