The Journal of organic chemistry

Syntheses and synthetic applications of stannylated allylic alcohols

U Kazmaier, S Lucas, M Klein

文献索引：Kazmaier, Uli; Lucas, Simon; Klein, Manuela Journal of Organic Chemistry, 2006 , vol. 71, # 6 p. 2429 - 2433

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被引用次数: 44

摘要

Allenyl carbinols undergo regioselective hydrostannation in the presence of MoBl3, a catalyst originally developed for the hydrostannation of alkynes, giving rise to allyl stannanes. These allyl stannanes can easily be converted into useful synthetic building blocks such as allyl iodides or vinyl epoxides.