Reversibility in the Formation of Oxo (peroxo) porphyrinatomolybdenums.

…, K Hoshiba, Y Sasaki, T Imamura

文献索引：Fujihara, Tetsuaki; Hoshiba, Koji; Sasaki, Yoichi; Imamura, Taira Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 2 p. 383 - 389

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被引用次数: 13

摘要

Reversibility in the formation reaction of a series of the oxo (peroxo) porphyrinatomolybdenums,[Mo VI O (tmp)(O 2)] 1,[Mo VI O (tdcpp)(O 2)] 2,[Mo VI O (ttp)(O 2)] 3,[Mo VI O (tdmpp)(O 2)] 4, and [Mo VI O (tpp)(O 2)] 5, was studied. In these dioxygen complexes with various porphyrin rings, two complexes, 2 and 4, were newly prepared by the solid-state reactions of corresponding Mo (IV) complexes with O 2. All the complexes ...