Mechanism of the reactions of oxomolybdenum (V) tetraphenylporphyrin complex with alcohols in the presence of superoxide

…, K Hasegawa, T Tanaka, W Nakajima…

文献索引：Imamura; Hasegawa; Tanaka; Nakajima; Fujimoto Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 1 p. 194 - 197

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被引用次数: 8

摘要

The successive addition of ROH (R= CH 3 and C 2 H 5) to the dichloromethane solution of Mo v O (tpp) Br (tpp= meso-tetraphenylporphinato) causes two-step reactions at 25° C. The products of the first and the second step of the reactions are alcohol complex,[Mo v O (tpp)(ROH)] Br, and alkoxo complex, Mo v O (tpp) OR, respectively. In the presence of superoxide ion, O 2−, in the dichloromethane solution of Mo v O (tpp) X (X= Br and NCS) ...