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Nucleophilicities of the Anions of Arylacetonitriles and Arylpropionitriles in Dimethyl Sulfoxide

O Kaumanns, R Appel, T Lemek…

文献索引:Adam, Waldemar; Makosza, Mieczyslaw; Zhao, Cong-Gui; Surowiec, Marek Journal of Organic Chemistry, 2000 , vol. 65, # 4 p. 1099 - 1101

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被引用次数: 37

摘要

... The Journal of Organic ... So far, only colored carbanions of relatively low nucleophilicity (N < 20) have been characterized.(5-10). In view of the frequent use of cyano substituted carbanions in organic synthesis, we have selected the carbanions 1a−c and 2a−c for systematic ... j ...