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Annelides. 7. Discotic mesophases obtained from substituted metallophthalocyanines. Toward liquid crystalline one-dimensional conductors

…, J Simon, A Skoulios, D Guillon, P Weber

文献索引:Piechocki, Christian; Simon, Jacques; Skoulios, Antoine; Guillon, Daniel; Weber, Patrick Journal of the American Chemical Society, 1982 , vol. 104, # 19 p. 5245 - 5247

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被引用次数: 506

摘要

Figure 2. Octasubstituted metallophthalocyanines synthesized. from metallophthalocyanines substituted with hydrocarbon chains should possess two interesting properties. First, the classical herring-bone structure found in the crystalline form of the PcM's is replaced in the columnar configuration by an untilted parallel stacking of the molecules. In the/3 form, the metal to metal distance is 4.85 A; an untilted stacking should decrease this value up to ...