Development of branching in living radical copolymerization of vinyl and divinyl monomers

I Bannister, NC Billingham, SP Armes…

文献索引：Bannister, Iveta; Billingham, Norman C.; Armes, Steven P.; Rannard, Steven P.; Findlay, Paul Macromolecules, 2006 , vol. 39, # 22 p. 7483 - 7492

全文：HTML全文

被引用次数: 143

摘要

The branching copolymerization of 2-hydroxypropyl methacrylate (HPMA) with either ethylene glycol dimethacrylate (EGDMA) or bisphenol A dimethacrylate (BPDMA) as the branching agent has been carried out using atom transfer radical polymerization (ATRP) in methanol at 20° C. With EGDMA, soluble branched copolymers were obtained provided that less than one branching agent was incorporated per primary chain: higher levels of ...