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Carbon networks based on dehydrobenzoannulenes: synthesis of graphdiyne substructures

MM Haley, SC Brand, JJ Pak

文献索引:Haley, Michael M.; Brand, Stephen C.; Pak, Joshua J. Angewandte Chemie, International Edition in English, 1997 , vol. 36, # 8 p. 835 - 838 Angewandte Chemie, 1997 , vol. 109, p. 863 - 866

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被引用次数: 187

摘要

Exploration into the formation of novel carbon allotropes continues to be an area of intense investigation."'To datc, most synthetic rcsearch has focused on planar polymeric networks comprising sp and. spz carbon Diederich et al. have prepared a variety of pcrethynylated monomers such as tetraeth~ nylethene,[~] tetraethynylb~ tatriene,~~~ and hexaethynyl [3] radialene.[51 Copper-mediated oxidative oligomerization of cis doubly deprotected ...