Carbon networks based on dehydrobenzoannulenes: synthesis of graphdiyne substructures

MM Haley, SC Brand, JJ Pak

Index: Haley, Michael M.; Brand, Stephen C.; Pak, Joshua J. Angewandte Chemie, International Edition in English, 1997 , vol. 36, # 8 p. 835 - 838 Angewandte Chemie, 1997 , vol. 109, p. 863 - 866

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Citation Number: 187

Abstract

Exploration into the formation of novel carbon allotropes continues to be an area of intense investigation."'To datc, most synthetic rcsearch has focused on planar polymeric networks comprising sp and. spz carbon Diederich et al. have prepared a variety of pcrethynylated monomers such as tetraeth~ nylethene,[~] tetraethynylb~ tatriene,~~~ and hexaethynyl [3] radialene.[51 Copper-mediated oxidative oligomerization of cis doubly deprotected ...