Tetrahedron: asymmetry

Preparation of (R)-sulforaphane by biotransformation using Helminthosporium species NRRL 4671

HL Holland, FM Brown, BG Larsen

文献索引：Holland, Herbert L.; Brown, Frances M.; Larsen, Brett G. Tetrahedron: Asymmetry, 1994 , vol. 5, # 7 p. 1129 - 1130

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被引用次数: 24

摘要

ABSTRACT: The fungus Helminthoprium species NRRL 4671 oxidizes I-isothiocyanato-4- ... (metbyltbio)butane to (->l-isothiocyanato-(4R)-(methylsulfinyl)butane (sulforaphane). Helminthoqorium ... In recent years, chiral sulfoxides have become incmasingly available as a result of developments in asynuuctric synthesis' and biotransformation.* Wc have carried out a systematic investigation of the ability of the fungus Helminthosprium species NRRL 4671 to perform asymmetric ...