Neuartige basische Liganden für die homogenkatalytische Methanolcarbonylierung: XVII. Dioxanylmethyldiorganylphosphane als Steuerliganden bei der Methanol ( …
E Lindner, A Sickinger, P Wegner
文献索引：Lindner, Ekkehard; Sickinger, Anselm; Wegner, Peter Journal of Organometallic Chemistry, 1988 , vol. 349, p. 75 - 94
Abstract The (ether-phosphane) ligands R 2 PCH 2 (1, 4-diox)(1a–c)(R= Ph (a), Mes (b), Cy (c); diox= dioxane residue) and Ph 2 PCH 2 (1, 3-diox)(2a) are obtained from the corresponding phosphides LiPR 2 and 2-chloromethyl-1, 4-dioxane and− 1, 3-dioxane, respectively, at− 40 C in ether. High pressure experiments can provide useful information on conversion and selectivity in the (hydro) carbonylation of methanol, if parameters like ...
