An Air??Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides

Z Weng, W He, C Chen, R Lee, D Tan…

文献索引：Weng, Zhiqiang; He, Weiming; Chen, Chaohuang; Lee, Richmond; Tan, Davin; Lai, Zhiping; Kong, Dedao; Yuan, Yaofeng; Huang, Kuo-Wei Angewandte Chemie - International Edition, 2013 , vol. 52, # 5 p. 1548 - 1552 Angew. Chem., 2013 , vol. 125, # 5 p. 1588 - 1592

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被引用次数: 149

摘要

Compounds that contain a trifluoromethylthio group (–SCF3) are found in many pharmaceutical and agrochemical products, such as Tiflorex and Vaniliprole.[1] Owing to their high lipophilicity and hydrophobicity, aryl trifluoromethylthioethers (ArSCF3) have attracted increasing attention from synthetic chemists. There have been considerable efforts in both academic and industrial laboratories towards achieving straightforward, efficient, ...