Tetrahedron

Copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with CF 3 CO 2 Na and elemental sulfur

L Zhai, Y Li, J Yin, K Jin, R Zhang, X Fu, C Duan

文献索引：Zhai, Lijuan; Li, Yaming; Yin, Jun; Jin, Kun; Zhang, Rong; Fu, Xinmei; Duan, Chunying Tetrahedron, 2013 , vol. 69, # 48 p. 10262 - 10266

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被引用次数: 35

摘要

Abstract A practical three-component copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with cheap and readily available sodium trifluoroacetate and elemental sulfur is reported. A variety of trifluoromethylthio-substituted aromatics are synthesized in moderate yields under mild reaction conditions.