Journal of heterocyclic chemistry

Acylation, cyanoethylation and alkylation of methyl and phenyl indolylmagnesium salts: Influence of the substituents on the c??and N??reaction products

JG Rodríguez, A Urrutia

文献索引：Rodriguez, J. Gonzalo; Urrutia, Anahi Journal of Heterocyclic Chemistry, 1999 , vol. 36, # 1 p. 129 - 135

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被引用次数: 10

摘要

Abstract Analysis of the influence of the substitution on indolylmagnesium salts in the reaction with benzoyl chlo ride, acrylonitrile and methyl iodide, giving the C-and N- derivatives, have been carried out. The yield in the C-and N-product depends upon the electronic character and position of the substituent (methyl or phenyl) on the indole ring and of the ethereal solvent as well as the concentration and molar ratio of the reagents. The 2- ...