The Journal of Organic Chemistry

Chemistry of N-halo compounds. 30. Regiospecific formation of azoxyaralkanes (diazene N-oxides) from N, N-dibromo compounds and nitrosobenzene

RC Zawalski, P Kovacic

文献索引：Zawalski,R.C.; Kovacic,P. Journal of Organic Chemistry, 1979 , vol. 44, p. 2130 - 2133

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被引用次数: 37

摘要

An niproved directed synthesis of azoxyaralkanes from. L', h'-dihromci compounds and nitrosobenzene is descriheti. Llnlike the prior related method. yields of'azoxy compounds are not sensitive to the nature of the. V,. Y-dihalo compound: Le.. high yields were obtained from all types (primary, secondary. and tertiary) of alkyl groups in RNHr:?. Several aspects of the mechanistic features are discussed.