A directed synthesis of alkyl, aryl, and heteroaryl-ONN-azoxycyanides

R Fruttero, G Mulatero, R Calvino…

文献索引：Fruttero, Roberta; Mulatero, Giovanna; Calvino, Rosella; Gasco, Alberto Journal of the Chemical Society, Chemical Communications, 1984 , # 5 p. 323 - 324

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被引用次数: 16

摘要

A variety of R-ONN-azoxycyanides can be prepared in high yield from the nitroso-derivatives with cyanamide and (diacetoxyiodo) benzene. ... Until now only two methods for the regiospecific synthesis of R-ONN-azoxycyanides (1) (R = aryl) have been reported, namely the dehydration of the corresponding amides (2) using thionyl chloride in dimethylformamide,l and the oxidation of the parent arenediazocyanides (aryldiazenecarbonitriles) (3) (R = aryl) with 85% ...