Gas–solid chlorination of 4-phenylthiazole-2 (1 H)-thione

V Nalini, GR Desiraju

文献索引：Nalini, Veerapaneni; Desiraju, Gautam R. Journal of the Chemical Society, Chemical Communications, 1987 , # 13 p. 1046 - 1048

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被引用次数: 0

摘要

The title compound (1) is converted into an unusual chlorophenacyl disulphide (2) through a crystal structure controlled Chlorination-oxidation reaction. ... Organic gas-solid reactions are interesting from both mechan- istic and stereochemical viewpoints. Recent work has shown that topochemical control plays an important role in determin- ing the course and outcome of these reactions.1-7 We report here a novel chlorination-oxidation of the title compound. ...