Practical electrochemical iodination of aromatic compounds

K Kataoka, Y Hagiwara, K Midorikawa…

文献索引：Kataoka, Kazuhide; Hagiwara, Yuji; Midorikawa, Koji; Suga, Seiji; Yoshida, Jun-Ichi Organic Process Research and Development, 2008 , vol. 12, # 6 p. 1130 - 1136

全文：HTML全文

被引用次数: 18

摘要

A practical method for electrochemical iodination of aromatic compounds was developed. The method involves the generation of I+ by electrochemical oxidation of I2 in CH3CN using H2SO4 as supporting electrolyte followed by the reaction with aromatic compounds. The para/ortho selectivity for the reaction of monosubstituted benzenes was significantly improved using dimethoxyethane as cosolvent in the second step. The reaction with ...