Tetrahedron Letters

Desulfonyloxyiodination of arenesulfonic acids with mCPBA and molecular iodine

Y Suzuki, Y Ishiwata, K Moriyama, H Togo

文献索引：Suzuki, Yuhsuke; Ishiwata, Yoshihide; Moriyama, Katsuhiko; Togo, Hideo Tetrahedron Letters, 2010 , vol. 51, # 45 p. 5950 - 5953

全文：HTML全文

被引用次数: 9

摘要

Treatment of p-alkylbenzenesulfonic acids with mCPBA and molecular iodine gave p- alkyliodobenzenes in good to moderate yields via electrophilic ipso-substitution by the iodonium species (I+) formed. This desulfonyloxyiodination was promoted by the addition of a catalytic amount of iodoarenes, such as o-iodobenzoic acid. The same treatment of dimethylbenzenesulfonic acids and trimethylbenzenesulfonic acids with mCPBA and ...

88-61-9

间二甲苯-4-磺酸水合物

~38%

4214-28-2

2,4-二甲基-1-碘苯

~57%

~63%

~70%

~22%

~82%

~7%

~59%

~45%

~83%

~31%

~89%

~63%

~17%

~66%

~47%

Aromatic iodination using N-iodosaccharin in room temperatur...

[Bailey, Lindsey; Handy, Scott T. Tetrahedron Letters, 2011 , vol. 52, # 18 p. 2413 - 2414]

Practical electrochemical iodination of aromatic compounds

[Kataoka, Kazuhide; Hagiwara, Yuji; Midorikawa, Koji; Suga, Seiji; Yoshida, Jun-Ichi Organic Process Research and Development, 2008 , vol. 12, # 6 p. 1130 - 1136]