Reactivities of nitrenes generated by photolysis of 2-(. omega.-phenylalkyl) phenyl azides

S Murata, R Yoshidome, Y Satoh, N Kato…

文献索引：Murata, Shigeru; Yoshidome, Ryuichi; Satoh, Youji; Kato, Noriyasu; Tomioka, Hideo Journal of Organic Chemistry, 1995 , vol. 60, # 5 p. 1428 - 1434

全文：HTML全文

被引用次数: 20

摘要

In order to investigate the reactivity of a photolytically generated arylnitrene with an intramolecular CH bond, the photochemistry of 2-(w-phenylalkyl) phenyl azides (la-d) was examined. Irradiation of 1 in solution revealed that the insertion of the nitrene into an adjacent CH bond to give cyclic compounds 4 and 6 occurs favorably only when a reactive CH bond, such as benzylic, is located close to the nitrenic center. This process can ...