Benzothiazoline: Versatile Hydrogen Donor for Organocatalytic Transfer Hydrogenation
…, K Saito, M Yamanaka, T Akiyama
文献索引：Saito, Kodai; Shibata, Yukihiro; Yamanaka, Masahiro; Akiyama, Takahiko Journal of the American Chemical Society, 2013 , vol. 135, # 32 p. 11740 - 11743
Conspectus The asymmetric reduction of ketimines is an important method for the preparation of amines in optically pure form. Inspired by the biological system using NAD (P) H, Hantzsch ester has been extensively employed as a hydrogen donor in combination with chiral phosphoric acid for the transfer hydrogenation of ketimines to furnish amines with high to excellent enantioselectivities. We focused on 2-substituted benzothiazoline as a ...
