Molecular and electronic structure of six-coordinate low-spin oxo-bridged dimers formed by the interaction of (. mu.-oxo) bis ((phthalocyaninato) iron (III)) with nitrogen …

C Ercolani, M Gardini, KS Murray, G Pennesi…

文献索引：Ercolani, Claudio; Gardini, Marcello; Murray, Keith S.; Pennesi, Giovanna; Rossi, Gentilina; Zwack, Peter R. Inorganic Chemistry, 1987 , vol. 26, p. 3539 - 3543

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被引用次数: 22

摘要

Crystalline bisadducts of general formula [(N-base) PcFeI20 have been prepared by the interaction of (p-oxo) bis ((phthalocyaninato) iron (III)) with vapors of liquid or liquid N-bases (pyridine, 4-methylpyridine, piperidine, 1-methylimidazole). Additional occluded molecules of the N-bases are also found present in the crystal lattice of these complexes. The molecular and electronic structure of the N-base adducts has been examined mainly on ...