Oxygen atom transfer in the oxidation of triphenylphosphine by µ-oxo-bis [phthalocyaninatoiron (III)]

C Ercolani, M Gardini, G Pennesi…

文献索引：Ercolani, Claudio; Gardini, Marcello; Pennesi, Giovanna; Rossi, Gentilina Journal of the Chemical Society, Chemical Communications, 1983 , # 10 p. 549 - 550

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被引用次数: 5

摘要

It has been shown that µ-oxo-bis [phthalocyaninatoiron (III)] can oxidize triphenylphosphine to triphenylphosphine oxide in the presence of pyridine under mild conditions, resulting in the formation of the corresponding FeII-bis adduct; this reaction is a rare example of O atom transfer by a µ-oxo FeIII oligomer.