A study of the catalytic deuteration of 1, 4-butynediol

…, JYJ Uang, TA Keiderling

文献索引：Chickos, James S.; Uang, Jack Y.-J.; Keiderling, Tim A. Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2594 - 2596

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被引用次数: 10

摘要

The stereoselective semihydrogenation of alkynes is an important and useful reaction in organic chemistry.'Recently, the stereoselective hydrogenation of 1, l-butynediol to 1P- butenediol using an interlamellar montmo-rillonite-diphenylphosphinepalladium (I1) complex has been reported. 2 The reaction proceeds with high selectivity (97%), and no reduction of the alkene was observed with the absorption of 1 equiv of hydrogen. We have ...