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Organic photochemistry with 6.7-eV photons:. gamma.,. delta.-unsaturated ketones

WJ Leigh, R Srinivasan

文献索引:Leigh, William J.; Srinivasan, R. Journal of the American Chemical Society, 1982 , vol. 104, # 16 p. 4424 - 4429

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被引用次数: 11

摘要

Abstract: The photochemistry of a series of acyclic, aliphatic y, &unsaturated ketones in pentane solution with 185-nm light has been investigated. The variety of products formed can be rationalized as arising from discrete reactions of the individually excited chromophores. Neither intramolecular energy transfer nor internal conversion leading to population of the lowest (n, r*) singlet state are competitive with product formation at 185 ...

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