Organic photochemistry with 6.7-eV photons:. gamma.,. delta.-unsaturated ketones

WJ Leigh, R Srinivasan

Index: Leigh, William J.; Srinivasan, R. Journal of the American Chemical Society, 1982 , vol. 104, # 16 p. 4424 - 4429

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Citation Number: 11

Abstract

Abstract: The photochemistry of a series of acyclic, aliphatic y, &unsaturated ketones in pentane solution with 185-nm light has been investigated. The variety of products formed can be rationalized as arising from discrete reactions of the individually excited chromophores. Neither intramolecular energy transfer nor internal conversion leading to population of the lowest (n, r*) singlet state are competitive with product formation at 185 ...