前往化源商城

Canadian journal of chemistry

Enzyme catalysed hydrolysis of chlorophenoxypropionates

R Chênevert, L D'astous

文献索引:Chenevert, Robert; D'Astous, Linda Canadian Journal of Chemistry, 1988 , vol. 66, p. 1219 - 1222

全文:HTML全文

被引用次数: 11

摘要

We report on the enzymatic hydrolysis of methyl 2-phenoxypropionate and of the following chlorinated derivatives: methyl o-chloro-, m-chloro-, p-chloro-, and o, p-dichloro-2- phenoxypropionates. α-Chymotrypsin, lipase, and pig liver esterase have an R enantioselectivity whereas subtilisin has an S enantioselectivity. Enantiomeric excesses (ee) cover a wide range (from 5 to 100%).