Palladium-Catalyzed Arylation of tert-Cyclobutanols with Aryl Bromide via CC Bond Cleavage: New Approach for the γ-Arylated Ketones

T Nishimura, S Uemura

文献索引：Nishimura, Takahiro; Uemura, Sakae Journal of the American Chemical Society, 1999 , vol. 121, # 47 p. 11010 - 11011

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被引用次数: 112

摘要

Palladium-catalyzed arylation of a wide variety of compounds with aryl halide has been developed in recent years as a powerful method to create an aromatic carbon-carbon bond1 as well as an aromatic carbon-heteroatom bond. 2 Recently, we have reported the palladium (II)-catalyzed oxidative ring cleavage of tert-cyclobutanols using oxygen as a reoxidant (Scheme 1), 3 in which we postulated that the CC bond of tert-cyclobutanols ...