Synthesis and reactivities of a novel flavoenzyme model, 5-deazaflavin with C 2-symmetry

R Yanada, Y Yoneda, M Yazaki, N Mimura, T Taga…

文献索引：Yanada, Reiko; Yoneda, Yoshiyuki; Yazaki, Mikako; Mimura, Norio; Taga, Tooru; Yoneda, Fumio; Yanada, Kazuo Tetrahedron Asymmetry, 1997 , vol. 8, # 14 p. 2319 - 2323

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被引用次数: 1

摘要

The title model compound represents a redox property of the active site of flavoenzymes and an environmental effect of the apoproteins. Its stereostructure was elucidated by 1H-NMR spectra and energy minimum calculations. The stereoselectivity of this model was observed during the reaction with Me2PNPH, as NAD (P) H model.