Homo-Favorskii rearrangement

E Wenkert, P Bakuzis, RJ Baumgarten…

文献索引：Wenkert,E. et al. Journal of the American Chemical Society, 1971 , vol. 93, # 13 p. 3208 - 3216

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被引用次数: 26

摘要

Abstract: The structures of the acidic products of the reaction between 3, 6-dimethyld- dichloromethyl-2-cyclo-hexenone and aqueous base have been revised. Full mechanistic and stereochemical analyses of the homo-Favor-skii rearrangement (base-induced dehydrochlorination of/3-haloketones, followed by scission of the resultant cyclobutanones in analogy with reactions of the Haller-Bauer type) of 6-dichloromethyl-6-methyl-2- ...