The Journal of Organic Chemistry

Beckmann Rearrangements in Alicyclic Systems. III. 2, 2-Dimethylcycloalkanone Oximes1, 2

RT Conley, BE Nowak

文献索引：Conley,R.T.; Nowak,B.E. Journal of Organic Chemistry, 1962 , vol. 27, p. 3196 - 3201

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被引用次数: 12

摘要

The Beckmann rearrangement of 2, 2-diniethylcyclopentanone, cyclohexanone, and cycloheptanone oximes has been examined. With either phosphorus pentachloride or thionyl chloride these oximes were cleaved to unsaturated nitriles. Only in the rearrangement of 2, 2-dimethylcyclohexanone oxime on treatment with benxenesulfonyl chloride or thionyl chloride was the lactarn expected from normal rearrangement obtained. ...