Chemical reviews

Comparison of phosphorus and silicon: Hypervalency, stereochemistry, and reactivity

RR Holmes

文献索引：Hacklin, Henrik; Roeschenthaler, Gerd-Volker Phosphorus and Sulfur and the Related Elements, 1988 , vol. 36, p. 165 - 170

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被引用次数: 416

摘要

... The results showed that as the sulfide was brought toward the phosphorus atom ... fact that the calculated reaction trajectory mimics that found for sulfur donor actions in ... B. Hexacoordinated Silicon In contrast to phosphorus, structural studies of hexacoordinated silicon compounds ...