Chemical reviews

Comparison of phosphorus and silicon: Hypervalency, stereochemistry, and reactivity

RR Holmes

Index: Hacklin, Henrik; Roeschenthaler, Gerd-Volker Phosphorus and Sulfur and the Related Elements, 1988 , vol. 36, p. 165 - 170

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Citation Number: 416

Abstract

... The results showed that as the sulfide was brought toward the phosphorus atom ... fact that the calculated reaction trajectory mimics that found for sulfur donor actions in ... B. Hexacoordinated Silicon In contrast to phosphorus, structural studies of hexacoordinated silicon compounds ...