Journal of Physical Chemistry

Matrix absorption spectra of the radicals formed by the addition of hydrogen atoms to phenylacetylene

L Andrews, BJ Kelsall

文献索引：Andrews, Lester; Kelsall, Benuel J. Journal of Physical Chemistry, 1987 , vol. 91, # 6 p. 1435 - 1440

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被引用次数: 7

摘要

Codeposition of hydrogen atoms from a blind discharge with phenylacetylene in argon at 20 K gave two new products with absorptions at 314.4, 474.7 nm and 346.9, 614.4 nm, respectively. These bands exhibited different photolysis behavior and are grouped accordingly. The former pair agree with assignments to a-styryl radical from radiolysis experiments, and the latter pair are assigned to the radical formed by hydrogen atom ...