Dynamics of radical pair reactions in micelles

IR Gould, MB Zimmt, NJ Turro, BH Baretz…

文献索引：Gould, I. R.; Zimmt, M. B.; Turro, N. J.; Baretz, B. H.; Lehr, G. F. Journal of the American Chemical Society, 1985 , vol. 107, # 16 p. 4607 - 4612

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被引用次数: 63

摘要

Abstract: The time-resolved behavior of sec-phenethyl, cumyl, and diphenylmethyl radicals as radical pairs solubilized in micelles has been observed using pulsed laser photolysis. The decay of the micellized radical pairs consists of a fast component (20-2000 X IO4 s), attributed to reaction within the geminate radical pair, and a slow component (> 2000 X lo4 s), attributed to reactions from random encounters of radicals. The extent of geminate pair ...