Journal of the American Chemical Society

Ligand effects on transition metal-alkyl bond dissociation energies

FTT Ng, GL Rempel

文献索引：Ng, Flora T. T.; Rempel, Garry L. Journal of the American Chemical Society, 1982 , vol. 104, # 2 p. 621 - 623

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被引用次数: 111

摘要

This additional contribution to the rate was reflected in the formation of a different product, namely, the aldehyde p-CH30C6H4CH2CH0, presumably by the reaction sequence of eq 19. Consistent with this interpretation, the product distribution was found to obey the relation [p-CH30C6H4CH2CHO]/[p-CH30C6H4CH3]= k19 [CO]/kl,, the aldehyde fraction increasing from 0 to 46% when the CO partial pressure was increased from 0 to 1 atm. Since the ...