Tetrahedron

Photosubstitution reactions on aromatic and heteroaromatic rings evidence for addition and substitution mechanism

B Šket, M Zupan, N Zupančič, B Pahor

文献索引：Sket, Boris; Zupan, Marko; Zupancic, Natasa; Pahor, Barbara Tetrahedron, 1991 , vol. 47, # 27 p. 5029 - 5042

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被引用次数: 6

摘要

Irradiation of a cyclohexane solution of hexafluorobenzene in the presence of benzophenone resulted in both, substitution and addition products. Similar photoreaction has been observed by irradiation of hexafluorobenzene in some alcohols in the presence of benzophenone. The reaction of pentafluorobenzene with methanol or cyclohexane resulted in the substitution of a 2-or 4-fluoro atom, while the reaction of pentafluoroanisole resulted ...