Supramolecular [M4L4] Tetrahedra Based on Triangular Acylhydrazone Catechol Ligands
…, Y Shang, T Rhyssen, J Stubenrauch…
文献索引：Albrecht, Markus; Shang, Yuli; Rhyssen, Tanja; Stubenrauch, Jan; Winkler, Henrik D. F.; Schalley, Christoph A. European Journal of Organic Chemistry, 2012 , # 12 p. 2422 - 2427
Abstract The ligands 1-H 6 and 2-H 6 are prepared by condensation of the triangular triamines 5 and 2, 3-dihydroxybenzoic acid hydrazide 7. The ligands form container-type tetrahedral coordination compounds M x [(1 or 2) 4 M′ 4](M= Li, Na, K; M′= Ti, x= 8; M′= Ga, x= 12). The complexes are characterized by NMR spectroscopy and ESI mass spectrometry. Despite the relatively labile acyl hydrazone unit, the complexes show high ...
[Van Den Broek, Sebastiaan A. M. W.; Leliveld, Jeroen R.; Becker, Rene; Delville, Marielle M. E.; Nieuwland, Pieter J.; Koch, Kaspar; Rutjes, Floris P. J. T. Organic Process Research and Development, 2012 , vol. 16, # 5 p. 934 - 938]
