Deoxygenation and desulfurization of organic compounds via transition metal atom cocondensation

…, BR Cho, M Hasegawa, JA Gladysz

文献索引：Togashi, Shigeo; Fulcher, John G.; Cho, Bong Rae; Hasegawa, Minoru; Gladysz, J.A. Journal of Organic Chemistry, 1980 , vol. 45, # 15 p. 3044 - 3053

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被引用次数: 16

摘要

Reactions3 resulting from the cocondensation of transition metal atoms with a variety of oxygen-and sulfur-containing organic compounds are surveyed. Alkenes are the major or exclusive volatile products when epoxides are reacted with Ti, V, Cr, Co, and Ni atoms. 2, 6- Dimethylpyridine N-oxide and dimethyl sulfoxide undergo deoxygenation upon cocondensation with chromium, but diisopropyl ether and decyl methyl ether do not. ...