Application of indium ate complexes to synthetic chemistry. Selective conjugate addition to enones and coupling with allylic halides

S Araki, T Shimizu, SJ Jin, Y Butsugan

文献索引：Araki, Shuki; Shimizu, Toshio; Jin, Shun-Ji; Butsugan, Yasuo Journal of the Chemical Society, Chemical Communications, 1991 , # 12 p. 824 - 825

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被引用次数: 26

摘要

Tetraorganoindium ate complexes, prepared by the addition of organolithium reagents to trialkylindium, reacted with α, β-unsaturated ketones in a 1, 4-addition fashion; allylic indates derived from allylic indium sesquihalides coupled with allylic halides regio-and stereo- specifically to give high yields of head-to-tail 1, 5-dienes.