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The Journal of Organic Chemistry

Palladium-catalyzed reaction of N-allylbenzotriazoles with amines: A novel method for the preparation of allylamines

AR Katritzky, J Yao, M Qi

文献索引:Katritzky, Alan R.; Yao, Jiangchao; Qi, Ming Journal of Organic Chemistry, 1998 , vol. 63, # 15 p. 5232 - 5234

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被引用次数: 20

摘要

Allylamines are common moieties in biologically active compounds1 and important intermediates in organic synthesis. Many syntheses of allylamines have been documented including (i) reaction of alkenyl cuprates with iminium salts, R-aminoethers or R- aminothioethers, 2 (ii) reaction of Grignard reagents with allyl-R-aminonitriles, 3 and (iii) the amination of dienes4 and allylic halides. 1a, 5 The most general approach is based on the ...